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I re-soldered the terminal and glued the fob back together and hey presto the central locking now works on the fob. I took the second fob apart and found the same issue with one of the battery terminals. I carried out the same repair but I haven't managed to get this fob to work with the central locking this time. I've tried the usual key reprogramming but as the battery was lower at 2.9v it might need charging on a longer journey to ramp the voltage up before it works.
So if anyone has issues with a key fob no longer activating their central locking and have tried reprogramming to no avail it might just be one of the battery terminals is no longer connected to the PCB. It is quite easy to split a key fob with a sharp blade such as a Stanley knife or scalpel and a pair of needle nose pliers (if you value your fingers) and a little bit of patience.